Answers are grounded in this paper and cite their sources.
A split decision: Efficient heterolytic hydrogen splitting is achieved with novel tetracoordinate rhodium(I) amides. This reaction is reversible, and DFT calculations imply that the cleavage is a one-step process with a relatively low activation barrier. Ketones and imines are hydrogenated by the amide complexes without the need for further additives.
No takes yet. Share an insight, caveat, or question.
Maire et al. (2005) studied this question.
Synapse has enriched 10 related papers. Consider them for comparative context: