Covalent post-synthetic modification of a MOF, (In) MIL-68-NH(2), is carried out in a novel fashion to immobilize amino acids within the structure. Solid-phase peptide coupling methodology opens new perspectives for anchoring chiral bio- and catalytically active species. This could facilitate the immobilization of highly active and/or coordinating moieties inside MOF cavities.
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Canivet et al. (2011) studied this question.
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