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No metal–substrate interactions: A transition-metal complex of a primary amine can serve as an efficient bifunctional metal–ligand catalyst that functions without direct interaction of the metal and the substrate. The example shows the transition-state structure of the enantioselective reduction of acetophenone at the molecular surface of a ruthenium hydride complex bearing a diamine with one free NH2 group (O red, Ru green, N blue).
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Kilian Muñiz (2005) studied this question.
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