From thermodynamic measurements, it is possible to identify the ligand atoms bound to Fe3f in nearly rhombic environments.D, the second rank axial coefficient in the spin Hamiltonian, is more than 4 times larger for primarily sulfur-ligated than for primarily oxygen-ligated high spin ferric iron.For the model in this study, rubredoxin, isolated from
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Peisach et al. (1971) studied this question.
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