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The first example of a mixed-metal amidoborane Na(2)Mg(NH(2)BH(3))(4) has been successfully synthesized. It forms an ordered arrangement in cation coordinations, i.e., Mg(2+) bonds solely to N(-) and Na(+) coordinates only with BH(3). Compared to ammonia borane and monometallic amidoboranes, Na(2)Mg(NH(2)BH(3))(4) can release 8.4 wt% pure hydrogen with significantly less toxic gases.
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Wu et al. (2011) studied this question.
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