LiNH2BH3·NH3BH3, synthesized by reacting LiH and 2 equiv of NH3BH3 or by reacting equiv LiNH2BH3 and NH3BH3, is composed of alternative LiNH2BH3 and NH3BH3 layers. The compound starts to release hydrogen at 57 °C and can desorb ca. 14.0 wt % hydrogen in a stepwise manner with peak temperatures at 80 and 140 °C, respectively.
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Wu et al. (2009) studied this question.
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