What question did this study set out to answer?

Determine the feasibility of observing indirect spin-spin J coupling between tellurium-125 and chlorine nuclei in solid-state materials using NMR spectroscopy.

June 1, 1987Journal of the American Chemical Society

CP/MAS tellurium-125 NMR in solids: an example of 125Te-35,37Cl J coupling

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Authors

MCMichael J. CollinsQueensland University of Technology JRJohn A. RipmeesterNational Research Council Canada JSJeffery F. SawyerCanarie

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Implication

Spectroscopic analysis demonstrates scalar J coupling between tellurium-125 and chlorine nuclei in solids, highlighting structural bonding interactions.

Key Points

Determine the feasibility of observing indirect spin-spin J coupling between tellurium-125 and chlorine nuclei in solid-state materials using NMR spectroscopy.
Employed solid-state cross-polarization magic-angle spinning (CP/MAS) tellurium-125 NMR spectroscopy.
Examined spectral splitting patterns resulting from interactions with 35Cl and 37Cl nuclei.
Resolved indirect spin-spin J coupling between tellurium-125 and the quadrupolar chlorine nuclei (35Cl and 37Cl) in solid crystalline form.
Demonstrated that solid-state CP/MAS NMR spectra provide direct detection of local tellurium-halogen bonding environments.

Cite This Study

Collins et al. (1987) studied this question.

synapsesocial.com/papers/6a92801d0b68d46265a286fa https://doi.org/10.1021/ja00247a047

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Implication

Spectroscopic analysis demonstrates scalar J coupling between tellurium-125 and chlorine nuclei in solids, highlighting structural bonding interactions.

CP/MAS tellurium-125 NMR in solids: an example of 125Te-35,37Cl J coupling

Discussion

Member takes

Implication

Key Points

Cite This Study

CP/MAS tellurium-125 NMR in solids: an example of 125Te-35,37Cl J coupling

Discussion

Member takes

Implication

Key Points

Cite This Study

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