The electron-induced characteristic x-ray emission from a noncentrosymmetric crystal shows a pronounced intensity difference when the Bragg condition is fulfilled for the G and -G reflections, respectively, along a polar direction. This two-beam effect is demonstrated fro GaAs and InP, and is a direct method of obtaining information about the phase of a structure factor and determining the sense of a polar direction.
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J. Taftø (1983) studied this question.
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