January 1, 2004Chemical Communications

Protonation of a lanthanum phosphide-alkyl occurs at the P–La not the C–La bond: isolation of a cationic lanthanum alkyl complex

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Abstract

Protonation of the heteroleptic, cyclometalated lanthanum phosphide complex [((Me3Si)2CH)(C6H4-2-CH2NMe2)P]La(THF)[P(C6H4-2-CH2NMe2)(CH(SiMe3)(SiMe2CH2))] with [Et3NH][BPh4] yields the cationic alkyllanthanum complex [(THF)4La[P(C6H4-2-CH2NMe2)(CH(SiMe3)(SiMe2CH2))]][BPh4].

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Izod et al. (2004) studied this question.

synapsesocial.com/papers/6a92d5c79da65ccb784a2720 https://doi.org/10.1039/b404188g

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Protonation of a lanthanum phosphide-alkyl occurs at the P–La not the C–La bond: isolation of a cationic lanthanum alkyl complex

Abstract

Discussion

Cite This Study

Protonation of a lanthanum phosphide-alkyl occurs at the P–La not the C–La bond: isolation of a cationic lanthanum alkyl complex

Abstract

Discussion

Cite This Study

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