The effect of presence of water on the transport of oxygen through films of Nylon‐6 was evaluated at 5, 23, and 40°C by permeation experiments. Through the oxygen permeability experiments it was found that the diffusion of oxygen through Nylon‐6 is not a simple Fickian process and the total diffusion process can be expressed by a bimodal diffusion mechanism. Permeability, solubility, and diffusion coefficients were determined as a function of water activity for both mechanisms. The effect of sorbed water on the oxygen diffusion and solubility in the polymer is presented as a function of the state of water in the polymer and as a result of the molecular competition between water and oxygen.
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Gavara et al. (1994) studied this question.
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