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The synthesis and free‐radical polymerization of four methacrylic macromonomers, methyl 6‐(6‐methacryloylaminohexanoylamino)hexanoate (5), methyl 11‐(11‐methacryloylaminoundecanoylamino)undecanoate (6), and the corresponding acids 7 and 8, are described. The polymers were characterized by DSC and TG analysis. Viscosity measurements show that the polymers tend to associate because of hydrogen bonding. Additionally, incompatibility of the polymers with polyamide‐6 was found by DSC measurements.
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Niemann et al. (1991) studied this question.
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