Spin-Dependent Final-State Interactions in Core Photoelectron Spectra of Metals with Incomplete Shell. II Numerical Computations

Overall line-shapes of the photoelectron spectra of core electrons in metals with incomplete shell are calculated numerically in details on the model proposed in a preceding paper. Three possible cases of the initial and final d -levels, which are of interest for those unfilled narrow-band metals, have been treated for the realistic values of various parameters. It has been found that the local line-shapes of numerical photoelectron spectra are well represented by the analytical ones for small s - d transfer energies but can become quite dissimilar to the latter when the s - d transfers increase. Recent experimental observations of the obscure multiplet-splittings in the transition metals are argued to be possibly interpreted in terms of the present model with fairly large s - d interaction strengths.