Aims.Numerous spectroscopic observations provide compelling evidence for a non-canonical mixing process that modifies the surface abundances of Li, C and N of low-mass red giants when they reach the bump in the luminosity function. Eggleton and collaborators have proposed that a molecular weight inversion created by the 3He(3He, 2p)4He reaction may be at the origin of this mixing, and relate it to the Rayleigh-Taylor instability. We argue that one is actually dealing with a double diffusive instability referred to as thermohaline convection and we discuss its influence on the red giant branch.
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