Nickel PCP-pincer hydride complexes catalyze chemoselective hydrosilylation of C═O bonds of aldehydes and ketones in the presence of other functional groups. The mechanism involves C═O insertion into a nickel−hydrogen bond, followed by cleavage of the newly formed Ni−O bond with a silane.
No takes yet. Share an insight, caveat, or question.
Chakraborty et al. (2008) studied this question.
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context: