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The electron spin resonance spectrum for the unstable radical CH3ĊHR in irradiated L-alanine was observed from 4.2–80°K. The hyperfine lines for MI = ± 1/2 showed relative maxima in peak intensity at 11°K when partially saturated. The presence of the maxima is interpreted in terms of spin-diffusion and Brownian mixing.
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Davidson et al. (1972) studied this question.
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