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The selectivity of supported gold catalysts in aerobic oxidation of cyclohexene under solvent-free conditions without addition of a radical initiator was tuned by either WO3 or the metal–organic framework MIL-101, used as a support/co-catalyst. WO3 was found to promote the formation of cyclohexene oxide via reaction of cyclohexenyl hydroperoxide with cyclohexene, while MIL-101 catalysed conversion of cyclohexenyl hydroperoxide to 2-cyclohexen-1-one.
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Ovoshchnikov et al. (2013) studied this question.
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