A new thiacalix[4]arene-cinnamaldehyde derivative 3, which undergoes red shift in the fluorescence spectrum in the presence of Ag(+) ions, has been synthesized. This emission shift is attributed to the intramolecular charge transfer process in the presence of Ag(+) ions with a detection limit in the nanomolar range.
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Kumar et al. (2011) studied this question.
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