Laboratory studies have been conducted to determine the influence of the composition of gas and oil phases on the parameters involved in the description of two-phase flow in porous media when the compositions of the phases vary over a wide range. Relative permeabilities to gas and oil were determined under high pressure and temperature for binary systems (methane/n-heptane, methane/n-decane, etc.), leading to very wide variations of the interfacial tensions values. Investigations were focused specifically on mixtures involving low interfacial tensions, down to 0.001 mN/m. This study has shown that residual oil saturations and relative permeabilities determined from the displacement tests with a filtration velocity of about 20 cm/hr are affected strongly by interfacial tension, especially when it is lower than 10−2 mN/m.
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Bardon et al. (1980) studied this question.
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