Radiolytic investigation uncovers reaction mechanisms of ethyl mercaptan with chemical scavengers, confirming strong proton acceptance and ion neutralization pathways.
The effect of electron, proton and radical scavengers on the radiolysis of ethyl mercaptan sensitized by argon has been studied. The mechanism suggested previously involving the neutralization of major positive ion has been confirmed. Ethyl mercaptan was found to be a very strong proton acceptor. The use of radical scavengers provided a valuable informations on reactions of sulphohydryl and thiyl radicals.
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Migedal et al. (1974) studied this question.
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