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Ag clusters (mean diameter = 1.5 nm, standard deviation = 0.37 nm) were photodeposited on TiO(2) particles in a highly dispersed state. The loading of a small amount of the Ag clusters (0.24 wt %) dramatically enhanced both the activity for the TiO(2) photocatalytic reduction of nitrobenzene and the product selectivity of aniline. The essential action mechanism of the Ag clusters is discussed.
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Tada et al. (2004) studied this question.
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