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Poly(β-hydroxybutyrate)s (PHB) of different microstructures were synthesized via anionic polymerization of β-butyrolactone initiated by two initiators: 1) supramolecular complexes of alkali metals with asymmetric induction agents, and 2) alkali metal alkoxides. The relationships between chemical microstructure and hydrolytic as well as thermal degradation properties of synthetic and natural PHB are discussed.
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Kurcok et al. (1995) studied this question.
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