The catalytically active complex in the homogeneously catalyzed, regioselective hydroformylation is possibly the dinuclear complex dication 1. The 1J(Rh,H) coupling constant of 164 Hz is the largest such value ever reported and may be a distinctive marker for dinuclear RhII complexes with terminal hydrido ligands.
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Matthews et al. (1996) studied this question.
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