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Progress has been made in probing the femtosecond of transition states of chemical reactions.(1) The "half-collision" case of unimolecular reactions has been investigated for a number of systems and theoretical work has already been developed.(2) For reactions, the case of full collision, the zero of is a problem which makes the femtosecond temporal of the dynamics a difficult task.
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Gruebele et al. (1991) studied this question.
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