Luminescence of Ca2LiSiO4F: Ce3+, Tb3+Phosphors

Ce 3+ , Tb 3+ singly-doped and co-doped Ca 2 LiSiO 4 F phosphors have been synthesized through conventional solid-state reaction. Their luminescence properties are studied. Under UV excitation, Ce 3+ singly-doped Ca 2 LiSiO 4 F phosphor emit blue light (460 nm), while Tb 3+ singly-doped phosphor presents yellowish green color with emission peaks at 414, 437, 486, 543, 588, and 620 nm. The excitation spectra of Ce 3+ and Tb 3+ co-doped Ca 2 LiSiO 4 F monitored at 543 nm show a strong broad excitation band in the UV region with a maximum at 362 nm. Excited at 370 nm, Ce 3+ and Tb 3+ co-doped Ca 2 LiSiO 4 F phosphor presents bluish white color with the emission peaks at 460, 486, 543, 588, and 620 nm. The energy transfer from Ce 3+ to Tb 3+ occurs in the co-doped Ca 2 LiSiO 4 F phosphors and is a resonance-type energy transfer due to the spectral overlap between the 460 nm emission of Ce 3+ and the excitation spectra monitored at 543 nm of Tb 3+ . The decay curves of 460 emission from Ce 3+ in the co-doped phosphors and the calculated lifetime results confirm the energy transfer. The results indicate that these phosphors have potential as phosphor candidates used for white LEDs pumped by UV chips.