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With the increasing use of physical methods of gas and vapour analysis, there is a need for a convenient means of calibration. It is confirmed that the use of gas and vapour mixtures stored in cylinders under pressure is a suitable method. Such mixtures are stable with time. The analysis of gas and vapour mixtures has been found to agree to within 1% of the calculated value.
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Dennis W. Hill (1961) studied this question.
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