Answers are grounded in this paper and cite their sources.
Oxovanadium clusters are intersting both as moels of bulk magnets and in their own right. Results are presented suggesting that in Na6[H6V12O30F2]·22H2O (see Figure) it is meaningful to decide which particular vanadium centers should be considered at 5⊕ and which as 4⊕. It is shown that in principle ist is possible to tune and design the topology, and thus the magnetic properties, of polyoxovanadates(IV/V) by means of the template effect. magnified image
No takes yet. Share an insight, caveat, or question.
Müller et al. (1993) studied this question.
Synapse has enriched 10 related papers. Consider them for comparative context: