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Three docking sites ensure that six guests jostle in the cavity of a new endo receptor. Three phenanthroline molecules are brought into close proximity by coordination of each with a CuI ion. In the FAB mass spectrometer the host complete with all six guests exists as the molecular supercomplex 1. Three bulky guest molecules are not„ invited”︁ simultaneously (R = CH3, p-C6H4CH3; R′ = H) because of the limited space in the cavity.
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Vögtle et al. (1991) studied this question.
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