Theoretical study demonstrates intrinsic viscosity dependencies in short polymer chains, suggesting improved hydrodynamic predictions for low-molecular-weight molecules.
The hydrodynamic theory of Kirkwood and Riseman is extended to include chains with a small number of bonds. The dependence of the intrinsic viscosity on the variation of the frictional coefficient, the chain statistics, and the number of bonds is analyzed.
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Perico et al. (1970) studied this question.
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