Preliminary results indicate the value of ion kinetic energy (1KE) spectra in adding a new dimension to structural information obtained by mass spectrometry. These spectra are especially useful in the distinction of some isomer pairs. Energy spectra provide a summary of gaseous ion chemistry occurring as metastable transitions in the first‐field free‐drift region of the double‐focusing (Mattauch‐Herzog geometry) mass spectrometer and are produced by scanning the electrostatic sector voltage while recording the ions transmitted by the sector with the beam monitor electrometer.
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Chait et al. (1971) studied this question.
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