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All articles of this category We describe the synthesis, structure ad DNA incorporation of a class of novel aromatic C-deoxynucleosides in which benzenes and larger polycyclic aromatics serve as DNA base analogs. Novel approaches have been developed for glycosidic bond formation and for epimerization of the anomeric substituents to β-configuration, and we describe some of the properties of such compounds in DNA. C-deoxynucleoside - β-anomer - α-anomer - organocadmium - glycosidation
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Chaudhuri et al. (1997) studied this question.
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