C-glycosylated biphenyls were prepared by the palladium-mediated cross-coupling reaction of C-glycosylated aryl tins with variously substituted aryl bromides, which will provide physiologically stable glycomimetics of various glycoepitopes. A C-sialylated biphenyl, a glycomimetic of biologically significant sialosides, is also available by this method.
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Kuribayashi et al. (1999) studied this question.
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