High-resolution ac calorimetry measurements on the nematic-smectic-A transition in liquid-crystal compounds, whose values of TNATNI range from 0.94 to 0.99, indicate a crossover point at a value of TNATNI equal to 0.96 between critical behavior where α⁺=α^- is less than or equal to zero to behavior characterized by α⁺=α^-=0.25.
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LeGrange et al. (1981) studied this question.
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