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Ferrocenyldithiodiphosphetane [FcPS(μ‐S)]2 [Fc = Fe(η5‐C5H4)(η5‐C5H5)] reacts with the aminoethanol derivatives 1‐ethyl‐3‐pyrrolidinol and 2‐(piperazin‐1‐yl)ethanol to give the zwitterionic (O‐ethylammonium)ferrocenyldithiophosphonates [FcP(S)S(C₄H₇NHEt)] (2) and [FcP(S)S(OC₂H₄NHC₄H₈NH)] (3), which were fully characterized by elemental analysis, IR and NMR spectroscopy and mass spectrometry. The optical and electrical properties of 2 and 3 as well as those of the previously reported [FcP(S)S(OC2H4NHEt2)] (1) were studied. A molecular structure determination of 1 is also reported.
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Karakuş et al. (2007) studied this question.
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