The rate constants for the production of vibrationally excited oxygen in the reactions O + CIO2 -----» O2(v''≤ 15) + CIO O + CIO -----» O2 (v''≤ 14) + Cl are approximately equal for all values of v" ≤ 13. The oxygen initially receives 45+10% of the heat of reaction in the form of vibrational energy. Extinction coefficients have been measured for several bands of the C-X, D -X and E -X systems of CIO2 in the vacuum ultraviolet. Five new systems are reported between 141 and 128 nm. Two of these, F-X and J-X , and the C-X system form a Rydberg series for an ionization potential of 10.36 eV.
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Basco et al. (1974) studied this question.
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