Organic matter in the sedimentary Biwabik iron formation in northern Minnesota shows a progressive increase in crystallinity where the formation is metamorphosed by the intrusive Duluth gabbro complex. X-ray diffraction of acid-insoluble residues shows that there is a complete range in crystallinity, from amorphous material in the unmetamorphosed sediments to completely crystalline graphite adjacent to the gabbro.
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Bevan M. French (1964) studied this question.
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