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Sterically congested pyrrole-fused tetrathiafulvalene (TTF) decamer 4 was designed and synthesized via the SNAr reaction of decafluorobiphenyl with the corresponding pyrrolyl sodium salt, which formed amorphous spin-coated films showing good conductivity of up to 4.4 S cm−1 after iodine doping as the result of multi-dimensional π–π stacking between the TTF units.
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Takase et al. (2012) studied this question.
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