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A Rh(III) -catalyzed C-H activation/cyclative capture approach, involving a nucleophilic addition of C(sp(3) )-Rh species to polarized double bonds is reported. This constitutes the first intermolecular catalytic method to directly access 1-aminoindolines with a broad substituent scope under mild conditions.
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Zhao et al. (2014) studied this question.
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