A rhodium(III)‐catalyzed direct selective C‐2 alkenylation reaction of indoles with alkenes has been developed with molecular oxygen as the sole oxidant. The rhodium/oxygen catalytic system is applicable to a broad range of indoles and alkenes, which provides a novel access to various C‐2 alkenylated indoles and pyrroles. magnified image
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Yang et al. (2014) studied this question.
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