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Rhodium-catalyzed highly regio- and stereoselective hydroselenation of internal alkynes bearing an electron-withdrawing group took place to give ( E )-vinyl selenides in good yields. The excellent syn stereoselectivity of this rhodium-catalyzed hydroselenation is of great importance in terms of complementing the previously reported hydroselenation of alkynes.
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Kawaguchi et al. (2011) studied this question.
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