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All articles of this category The choice of electronic environment about the metal atom is crucial to the observed selectivity in the Rh(I)-catalysed [4 + 2] cycloaddition. An account of the influence of the counterion on the rate, diastereo-, enantio- and product selectivity is described. rhodium catalysed [4 + 2] - counterion effects - hexafluoroantimonate - Diels-Alder reaction - hexahydroisoindoles
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O’Mahony et al. (1998) studied this question.
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