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Three efficient, high yieldmg syntheses of precursors (1) of carbamoylpolyoxamic acid from L-arabinose, based on the simultaneous addition of the acid and amine functionalities, are described.Utilizing the same methodology and uridie as the starting material, an expedient 3 step (61% overall yield) synthesis of protected uracil polyoxin C (or the nucleoside moiety of polyoxin L, 2), is also described.
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Kutterer et al. (1999) studied this question.
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