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A convenient synthesis of theN-protected Lcarbamoylpolyoxamic acid derivative (7) From 4-0-tert-butyldiphenylsilyl-2,3isopropylidene-L-threose (8) using vinylmagnesium bromide and its application to the total syntheses of the peptidyl nucleoside antibiotics, polyoxins J (1) and L (2), are described.
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Akita et al. (1998) studied this question.
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