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A heterotridentate (P,N,N‘) ligand featuring phosphine, iminophosphorane, and amine groups has been prepared in high yield. The corresponding dichlororuthenium(II) complex reacts with base in 2-propanol to give a stable hydrido amido complex. The lack of hydrogens that are α to the amine allowed for the isolation and structural characterization of this hydrido amido species by X-ray diffraction.
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Boubekeur‐Lecaque et al. (2005) studied this question.
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