Tuning with zinc: Palladium complexes of 3-pyridyl-bian (see scheme, blue) provide active catalysts for the copolymerization of CO and 4-tert-butylstyrene, but only after encapsulation by two zinc salphen building blocks (red). The catalyst properties depend on the salphen units, giving rise to novel tools for catalyst tuning.
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Flapper et al. (2007) studied this question.
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