The odd couple: Inspired by the principle of DNA base pairing a conceptually new approach for the generation of a heterobidentate-ligand library based on self-assembly through hydrogen-bonding is realized. From a 4×4 library a catalyst that shows outstanding activity and excellent regioselectivity could be identified (see scheme; FGR=functional group, Do=donor group).
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Breit et al. (2005) studied this question.
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