Selectivity from a rigid sandwich-type complex: A supramolecular approach was used to prepare chelating ligands that give high selectivity for the linear aldehyde in the rhodium-catalyzed hydroformylation of 1-octene. The multicomponent assembly consists of two tris(zinc(II) porphyrin)phosphite ligands (blue) and three ditopic templates (red) with the rhodium complex (green) in the middle of the structure.
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Slagt et al. (2003) studied this question.
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