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Well mixed: A 1:1 mixture of two different binaphthol-derived monophosphonite ligands (L) is employed in the Rh-catalyzed hydrogenation of prochiral olefins (see scheme; cod=cyclooctadiene). Variation of the enantiopurity of the ligands results in unusual nonlinear effects; furthermore, >92 % ee can be achieved even if one component is racemic.
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Reetz et al. (2006) studied this question.
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