Answers are grounded in this paper and cite their sources.
The coordination mode of a monodentate phosphoroamidite ligand in a rhodium complex can be switched from equatorial to axial by a unique supramolecular pseudo encapsulation (see scheme). The axial complex has higher activity and selectivity in the challenging asymmetric hydroformylation of internal alkenes.
No takes yet. Share an insight, caveat, or question.
Bellini et al. (2011) studied this question.
Synapse has enriched 10 related papers. Consider them for comparative context: