Visible-light irradiation of the hexafluorophosphate salt of [Cp*IrIII(bpy)H]+ (1, Cp*=η5-C5Me5, bpy=2,2′-bipyridine) results in excited-state deprotonation to form the conjugate base [Cp*IrI(bpy)]. The H/D exchange reaction of 1 also occurs during photoirradiation of 1 in [D4]methanol in the steady state (see picture).
No takes yet. Share an insight, caveat, or question.
Suenobu et al. (2003) studied this question.
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context: