Multifunctional Nanoparticle‐Loaded Spherical and Wormlike Micelles Formed by Interfacial Instabilities

Hybrid spherical and wormlike amphiphilic block copolymer micelles are formed through evaporation-induced interfacial instabilities of emulsion droplets, allowing the incorporation of pre-synthesized hydrophobic inorganic nanoparticles within the micelle cores, as well as co-encapsulation of different nanoparticles. This encapsulation behavior is largely insensitive to particle surface chemistry, shape, and size, thus providing a versatile route to fabricate multifunctional micelles.